Fluorimetric characterization of single-walled carbon nanotubes.

نویسنده

  • R Bruce Weisman
چکیده

Single-walled carbon nanotubes (SWCNTs) are a family of structurally related artificial nanomaterials with unusual properties and many potential applications. Most SWCNTs can emit spectrally narrow near-IR fluorescence at wavelengths that are characteristic of their precise diameter and chiral angle. Near-IR fluorimetry therefore offers a powerful approach for identifying the structural species present in SWCNT samples. Such characterization is increasingly important for nanotube production, study, separation, and applications. General-purpose and specialized instruments suitable for SWCNT fluorimetric analysis are described, and methods for interpreting fluorimetric data to deduce the presence and relative abundances of different SWCNT species are presented. Fluorescence methods are highly effective for detecting SWCNTs in challenging samples such as complex environmental or biological specimens because of the methods' high sensitivity and selectivity and the near absence of interfering background emission at near-IR wavelengths. Current limitations and future prospects for fluorimetric characterization of SWCNTs are discussed.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis and characterization of functionalized single - walled carbon nanotube/ chitosan/polyaniline nanocomposite

In this work the synthesis of polyaniline/chitosan/functionalized single- walled carbon nanotube nanocomposite is carried out. For this purpose single -walled carbon nanotubes were reacted with thionyl chloride to change the hydroxyl to acyl chloride groups for improving the react ability. In other step, aniline monomers and chitosan were polymerized in the presence of Iron (III) chloride to sy...

متن کامل

Synthesis and characterization of functionalized single - walled carbon nanotube/ chitosan/polyaniline nanocomposite

In this work the synthesis of polyaniline/chitosan/functionalized single- walled carbon nanotube nanocomposite is carried out. For this purpose single -walled carbon nanotubes were reacted with thionyl chloride to change the hydroxyl to acyl chloride groups for improving the react ability. In other step, aniline monomers and chitosan were polymerized in the presence of Iron (III) chloride to sy...

متن کامل

A PARAMETRIC STUDY ON THE GROWTH OF SINGLE-WALLED CARBON NANOTUBES OVER CO-MO/MGO NANOCATALYST IN A FLUIDIZED BED REACTOR BY CCVD METHOD

Single-walled carbon nanotubes (SWNTs) with high yield and quality were synthesized using chemical vapor deposition (CVD) over Co-Mo/ MgO nanocatalyst in a fluidized bed reactor. Different parameters such as temperature, the ratio of hydrocarbon source to hydrogen, the flow rate of gas, growth time, the size of catalyst particles, heating rate, and the kind of hydrocarbon source were examined t...

متن کامل

Structure-assigned optical spectra of single-walled carbon nanotubes.

Spectrofluorimetric measurements on single-walled carbon nanotubes (SWNTs) isolated in aqueous surfactant suspensions have revealed distinct electronic absorption and emission transitions for more than 30 different semiconducting nanotube species. By combining these fluorimetric results with resonance Raman data, each optical transition has been mapped to a specific (n,m) nanotube structure. Op...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Analytical and bioanalytical chemistry

دوره 396 3  شماره 

صفحات  -

تاریخ انتشار 2010